Adapted from Nigella Lawson
Pouring boiling water directly into a cold batter will scramble the eggs and seize the melted chocolate. Prevent this structural failure by incorporating the liquids in strict stages, melting the chocolate first so it cools for exactly ten minutes before hitting the bowl. Room-temperature butter at 68 degrees Fahrenheit integrates into the dry flour and cocoa mixture without creating greasy pockets, ensuring a uniform crumb structure when using gluten-free starches.
Divide the batter evenly between two 21 x 11cm loaf tins and bake at 350 degrees Fahrenheit until a skewer inserted into the center emerges clean, typically requiring fifty to sixty minutes. Piercing the warm cake immediately after baking allows the boiled sugar-and-cocoa syrup to penetrate the interior matrix rather than pooling on the surface. Leaving the parchment paper handles intact during this soaking phase provides structural support while the crumb absorbs the liquid.
Wrapped tightly in plastic wrap, this dense loaf actually improves on the second day as the starches fully hydrate and the chocolate flavor deepens.