Try this How to Caramelize Onions recipe, or contribute your own.
Using a wide-bottomed stainless steel or cast-iron skillet maximizes the surface area exposed to heat, encouraging even moisture evaporation across every single slice. When the pan begins accumulating sticky brown fond too quickly, introducing a single tablespoon of water deglazes the surface and redistributes those savory compounds back into the softening vegetables. Monitoring the process closely over a full sixty-minute window ensures the final product achieves a deep amber hue without any acrid bitterness.
Direct heat must be modulated carefully from medium-high down to medium as the initial water content releases from the cellular structure. Salt added at the beginning draws out moisture via osmosis, accelerating the softening phase before browning officially commences. If the edges darken too rapidly before the centers turn tender, reducing the burner to low protects the sugars from burning prematurely.
Heavy-bottomed vessels distribute thermal energy more uniformly than thin aluminum pans, eliminating hot spots that cause uneven cooking. Once finished, these soft Alliums keep safely in a refrigerated container for up to one week or transfer to the freezer for storage lasting several months.