This is a spin on a Paula Dean recipe; I just switched a few things around.
Searing bone-in pork chops for precisely four minutes per side requires maintaining a medium-high skillet temperature to build an even crust without burning the brown sugar in the rub. Fat content matters significantly here, as lean cuts dry out faster when exposed to high heat.
Transferring the seared meat to a preheated 350 degree oven allows the interior to cook through during the thirty-five minute baking window. Bone-in cuts conduct heat differently than boneless options, affecting the internal temperature progression during this roasting phase.
Dry spices like garlic powder and onion powder blend uniformly with cocoa powder to create a distinct aromatic barrier over the meat surface. Substituting fresh minced garlic or fresh onions introduces excess moisture that prevents proper browning and alters the crust formation entirely.
Measuring exact quantities ensures the balance between bitter cocoa and sweet brown sugar remains stable across batches. Allowing the spice blend to rest on the meat for ten minutes before cooking helps the dry ingredients adhere to the surface without sliding off into the hot pan oil.